الجمعة، 10 أغسطس 2012

Isentropic Flow

Isentropic Flow


Figure 4.1: Flow thorough a converging diverging nozzle
\begin{figure}\centerline{\includegraphics {cont/variableArea/nozzle}}
\end{figure}
In this chapter a discussion on a steady state flow through a smooth and continuous area flow rate is presented. A discussion about the flow through a converging-diverging nozzle is also part of this chapter. The isentropic flow models are important because of two main reasons: One, it provides the information about the trends and important parameters. Two, the correction factors can be introduced later to account for deviations from the ideal state. 

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Speed of Sound in Solids

The situation with solids is considerably more complicated, with different speeds in different directions, in different kinds of geometries, and differences between transverse and longitudinal waves. Nevertheless, the speed of sound in solids is larger than in liquids and definitely larger than in gases.
Young's Modulus for a representative value for the bulk modulus for steel is 160 $ 10^9$ N /$ m^2$ .
Table 3.3: Solids speed of sound, after Aldred, John, Manual of Sound Recording, London:Fountain Press, 1972
material reference Value [m/sec]
Diamond   12000
Pyrex glass   5640
Steel longitudinal wave 5790
Steel transverse shear 3100
Steel longitudinal wave (extensional wave) 5000
Iron   5130
Aluminum   5100
Brass   4700
Copper   3560
Gold   3240
Lucite   2680
Lead   1322
Rubber   1600

Speed of sound in solid of steel, using a general tabulated value for the bulk modulus, gives a sound speed for structural steel of

Compared to one tabulated value the example values for stainless steel lays between the speed for longitudinal and transverse waves.

Speed of Sound in Almost Incompressible Liquid

Even liquid normally is assumed to be incompressible in reality has a small and important compressible aspect. The ratio of the change in the fractional volume to pressure or compression is referred to as the bulk modulus of the material. For example, the average bulk modulus for water is $ 2.2 \times 10^9$ $ N/m^2$ . At a depth of about 4,000 meters, the pressure is about $ 4 \times 10^7$ $ N/m^2$ . The fractional volume change is only about 1.8% even under this pressure nevertheless it is a change.
The compressibility of the substance is the reciprocal of the bulk modulus. The amount of compression of almost all liquids is seen to be very small as given in Table (3.5). The mathematical definition of bulk modulus as following

In physical terms can be written as

For example for water
$\displaystyle c = \sqrt{2.2 \times 10^9 N /m^2 \over 1000 kg /m^3} = 1493 m/s %\label{sound:eq:waterSpeed}
$    

This agrees well with the measured speed of sound in water, 1482 m/s at $ 20^{\circ}C$ . Many researchers have looked at this velocity, and for purposes of comparison it is given in Table (3.5)

Table 3.1: Water speed of sound from different sources
Remark reference Value [m/sec]
Fresh Water ( $ 20^{\circ}C$ ) Cutnell, John D. & Kenneth W. Johnson. Physics. New York: Wiley, 1997: 468. 1492
Distilled Water at ( $ 25^{\circ}C$ ) The World Book Encyclopedia. Chicago: World Book, 1999. 601 1496
Water distilled Handbook of Chemistry and Physics. Ohio: Chemical Rubber Co., 1967-1968:E37 1494

The effect of impurity and temperature is relatively large, as can be observed from the equation (3.37). For example, with an increase of 34 degrees from $ 0 ^{\circ}C$ there is an increase in the velocity from about 1430 m/sec to about 1546 [m/sec]. According to Wilson3.5, the speed of sound in sea water depends on temperature, salinity, and hydrostatic pressure.
Wilson's empirical formula appears as follows:

where $ c_0 = 1449.14[m/sec]$ is about clean/pure water, $ c_{T}$ is a function temperature, and $ c_S$ is a function salinity, $ c_P$ is a function pressure, and $ c_{STP}$ is a correction factor between coupling of the different parameters.

Table 3.2: Liquids speed of sound, after Aldred, John, Manual of Sound Recording, London: Fountain Press, 1972
material reference Value [m/sec]
Glycerol   1904
Sea water $ 25^{\circ}C$ 1533
Mercury   1450
Kerosene   1324
Methyl alcohol   1143
Carbon tetrachloride   926

In summary, the speed of sound in liquids is about 3 to 5 relative to the speed of sound in gases

Speed of Sound in Real Gas

The ideal gas model can be improved by introducing the compressibility factor. The compressibility factor represents the deviation from the ideal gas. 

\begin{figure}\centerline{\includegraphics
{cont/sound/CompressiblityChart}}
\end{figure}
Figure: The Compressibility Chart
\begin{figure}\centerline{\includegraphics
{cont/sound/CompressiblityChart}}
\end{figure}
Thus, a real gas equation can be expressed in many cases as

The speed of sound of any gas is provided by equation (3.7). To obtain the expression for a gas that obeys the law expressed by (3.19) some mathematical expressions are needed. Recalling from thermodynamics, the Gibbs function (3.20) is used to obtain
$\displaystyle Tds = dh - {dP \over \rho}$

The definition of pressure specific heat for a pure substance is

The definition of volumetric specific heat for a pure substance is

From thermodynamics, it can be shown 3.4

The specific volumetric is the inverse of the density as $ v = zRT/P$ and thus

Substituting the equation (3.24) into equation (3.23) results

Simplifying equation (3.25) to became
$\displaystyle dh = C_p dT - \left[ {T v \over z} \left( \partial z \over \parti...
...ver z}\left(\partial z \over \partial T \right)_P {dP \over \rho} %\label{eq:}
$ (3.26)

Utilizing Gibbs equation (3.20)

Letting $ ds =0$ for isentropic process results in

Equation (3.28) can be integrated by parts. However, it is more convenient to express $ dT / T$ in terms of $ C_v$ and $ d\rho / \rho$ as follows

Equating the right hand side of equations (3.28) and (3.29) results in

Rearranging equation (3.30) yields

If the terms in the braces are constant in the range under interest in this study, equation (3.31) can be integrated. For short hand writing convenience, $ n$ is defined as

Note that $ n$ approaches $ k$ when $ z\rightarrow1$ and when $ z$ is constant. The integration of equation (3.31) yields

Equation (3.33) is similar to equation (3.11). What is different in these derivations is that a relationship between coefficient n and $ k$ was established. This relationship (3.33) isn't new, and in-fact any thermodynamics book shows this relationship. But the definition of n in equation (3.32) provides a tool to estimate n . Now, the speed of sound for a real gas can be obtained in the same manner as for an ideal gas.


\begin{examl}
Calculate the speed of sound of air
at $30\celsius$ and atmospher...
...as model
(compressibility factor).
Assume that $R = 287 [j /kg /K]$.
\end{examl}
SOLUTION $ \;$
According to the ideal gas model the speed of sound should be
$\displaystyle c = \sqrt{kRT} = \sqrt{1.407 \times 287 \times 300} \sim 348.1[m/sec]$    

For the real gas first coefficient $ n = 1.403 $ has
$\displaystyle c = \sqrt{znRT} = \sqrt{1.403 \times 0.995 times 287 \times 300} = 346.7 [m/sec]$    

Solution
According to the ideal gas model the speed of sound should be
$\displaystyle c = \sqrt{kRT} = \sqrt{1.407 \times 287 \times 300} \sim 348.1[m/sec]$    

For the real gas first coefficient $ n = 1.403 $ has
$\displaystyle c = \sqrt{znRT} = \sqrt{1.403 \times 0.995 times 287 \times 300} = 346.7 [m/sec]$    


The correction factor for air under normal conditions (atmospheric conditions or even increased pressure) is minimal on the speed of sound. However, a change in temperature can have a dramatical change in the speed of sound. For example, at relative moderate pressure but low temperature common in atmosphere, the compressibility factor, $ z=0.3$ and $ n\sim 1$ which means that speed of sound is only $ \sqrt{0.3 \over 1.4}$ about factor of (0.5) to calculated by ideal gas model